XPS peak data for adlayers on gold. The normalized area is corrected by a sensitivity factor to take into account the photoionization cross section of the orbital involved.
Compound 180 (prepared using triphenylsilane thiol).
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Cu 2p3/2 |
933 |
41721 |
9934 |
|
O 1s |
533 |
63158 |
95694 |
|
N 1s |
400 |
12179 |
28997 |
|
C 1s |
285 |
217907 |
871629 |
|
S 2p |
163 |
12338 |
22849 |
|
Au 4f |
84 |
3069903 |
620182 |
Compound 181 (prepared using triphenylsilane thiol).
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Cu 2p3/2 |
932 |
83853 |
19965 |
|
O 1s |
532 |
62212 |
94261 |
|
N 1s |
400 |
14626 |
34824 |
|
C 1s |
285 |
185473 |
741893 |
|
S 2p |
163 |
15889 |
29424 |
|
Au 4f |
84 |
3160029 |
638390 |
Compound 223.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
O 1s |
533 |
29507 |
44707 |
|
N 1s |
400 |
18983 |
45199 |
|
C 1s |
285 |
277768 |
1111071 |
|
S 2p |
163 |
7461 |
13817 |
|
Au 4f |
84 |
3057556 |
617688 |
Compound 224.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Zn 2p3/2 |
1022 |
79408 |
16543 |
|
O 1s |
533 |
34690 |
52560 |
|
N 1s |
398 |
20339 |
48427 |
|
C 1s |
285 |
299005 |
1196019 |
|
S 2p |
162 |
12967 |
24014 |
|
Au 4f |
84 |
2694332 |
544310 |
Compound 227.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
O 1s |
533 |
22841 |
34607 |
|
N 1s |
400 |
19554 |
46557 |
|
C 1s |
285 |
312345 |
1249382 |
|
S 2p |
162 |
4395 |
8139 |
|
Au 4f |
84 |
3350724 |
676914 |
Compound 228.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Zn 2p3/2 |
1022 |
49235 |
10257 |
|
O 1s |
531 |
31998 |
48483 |
|
N 1s |
398 |
11908 |
28353 |
|
C 1s |
285 |
204552 |
818206 |
|
S 2p |
163 |
5724 |
10600 |
|
Au 4f |
84 |
3283346 |
663302 |
Compound 229.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Ni 2p3/2 |
855 |
46807 |
15602 |
|
O 1s |
533 |
29349 |
44468 |
|
N 1s |
399 |
22660 |
53953 |
|
C 1s |
285 |
309847 |
1239387 |
|
S 2p |
162 |
5728 |
10608 |
|
Au 4f |
84 |
2933022 |
592530 |
Compound 260.
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
Cu 2p3/2 |
932 |
30696 |
4872 |
|
O 1s |
533 |
159999 |
242423 |
|
Os 4p3/2 |
472 |
70706 |
70706 |
|
N 1s |
400 |
6423 |
15293 |
|
C 1s |
288 |
105584 |
422339 |
|
C 1s |
285 |
363860 |
1455440 |
|
S 2p |
163 |
12103 |
22413 |
|
Au 4f |
84 |
2945294 |
595009 |
Bare gold (as evaporated, exposed to air).
|
Peak |
Centre (eV) |
Area |
Normalized area |
|
C 1s |
285 |
112577 |
450307 |
|
Au 4f |
84 |
4589302 |
927132 |